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Phthalate-Free Plasticizer ATBC

An eco-friendly, bio-based, and non-toxic primary plasticizer engineered as a seamless premium alternative to ortho-phthalates, delivering exceptional safety, clarity, and processing fluidics for sensitive consumer, medical, and elastomer applications.

In modern polymer compounding, medical elastomer engineering, and regulated consumer manufacturing, transitioning to sustainable raw materials without compromising physical flexibility is a major operational target. Acetyl Tributyl Citrate (universally prioritized in global green procurement as ATBC) operates as a leading bio-base, phthalate-free primary plasticizer. Chemically derived from natural citric acid fermentation pathways (CAS No. 77-90-7), ATBC is a clear, water-white, practically odorless liquid. Thanks to its superb toxicological profile and excellent compatibility with polar matrices like PVC, polyurethane, and nitrile rubbers, ATBC stands as the industry-trusted choice to replace restricted ortho-phthalates (like DOP, DBP, and DIBP) in high-compliance formulations.

Technical Product Specifications

Property / Parameter Standard Specification (Premium Grade)
Chemical Name Acetyl Tributyl Citrate (ATBC)
CAS Number 77-90-7
Molecular Formula C20H40O8
Assay / Active Purity (%) ≥ 99.5%
Color (APHA / Pt-Co) ≤ 30 max
Density (g/cm³ at 20°C) 1.045 – 1.055 g/cm³
Acidity (as Citric Acid, %) ≤ 0.02%
Flash Point (°C, Open Cup) ≥ 204 °C

Why Choose Our ATBC Plasticizer?

  • ✓ Non-Toxic and Biocompatible Profile: Completely free of ortho-phthalate structures, fully matching the global regulatory demands of EU REACH Annex XIV, US FDA food-contact mandates, and strict medical-grade parameters.
  • ✓ Superior Melt Fluidity and Wetting: Its localized ester network reduces polymer internal viscosity, optimizing pigment wetness, compounding output, and surface leveling traits during thermal processing.
  • ✓ Excellent Light and Heat Weathering: Exhibits notable resistance to solar yellowing and thermal extraction loops, ensuring modified elastomers stay soft and elastic without brittle cracking.

Primary Applications

Phthalate-free ATBC is extensively formulated into high-compliance vinyl coatings, medical elastomers, and food-grade packaging films:

Medical Devices & Care Products

The industry benchmark plasticizer for non-toxic medical tubing, blood storage bags, respiratory masks, surgical gloves, and clear pharmaceutical components.

Food-Contact Packaging & Toys

Extensively selected for clear food-wrap films, beverage caps, soft children’s toys, pacifiers, and consumer health elements requiring absolute chemical neutrality.

Nitrile & Polyurethane Modification

Used in polar rubbers like NBR, PU, and acrylic coatings to decrease compounding friction, improve cold weather flex, and serve as an eco-friendly carrier matrix.

⚠ Storage & Handling Guidelines

Maintaining correct warehouse climate parameters is vital to protect the active ester purity and excellent water-white clarity of Acetyl Tributyl Citrate (ATBC). Although it possesses outstanding chemical stability and a high flash point, its bio-based ester bonds can undergo slow hydrolysis if exposed to prolonged moisture tracks, impacting its acid value and performance metrics.

  • • Warehouse Climate Control: Store all liquid drums, IBC totes, or bulk storage tanks within a thoroughly cool, dry, and well-ventilated dedicated warehouse footprint. Keep storage rows completely isolated from direct sunlight, open flames, steam pipes, or heating grids.
  • • Airtight Sealing Management: Ensure all container bungs, valves, and caps are tightly resealed immediately after any dispensing or sampling operations. Keeping containers hermetically sealed prevents ambient humidity absorption and safeguards the low-acidity quality of the ester.
  • • Shelf Life & Rotation Strategy: Under clean, temperature-controlled, and sealed environment parameters, our premium ATBC plasticizer carries a certified shelf life of 24 months from the date of manufacture. Adhering to a strict First-In, First-Out (FIFO) material rotation system is recommended.

Frequently Asked Questions

Is ATBC a direct drop-in replacement for DOP in medical PVC tubing formulations? +
Yes. ATBC exhibits excellent solvating power and a high plasticizing efficiency that closely tracks that of DOP (DEHP). It can be integrated directly into medical PVC or polyurethane extrusion lines using similar temperature profiles, providing equivalent mechanical flexibility and kink resistance while eliminating ortho-phthalate toxicity concerns.
How does ATBC behave regarding migration and extraction in food-contact films? +
Due to its robust molecular weight and long ester groups, ATBC offers very low volatility and strong resistance to migration in fatty or aqueous environments. This minimal leaching makes it highly compliant with US FDA and EU food-contact standards, ensuring wrap films and closures remain soft and safe throughout their shelf life.
What is the typical dosage window for ATBC in environmental rubber compounding? +
In eco-friendly nitrile rubber (NBR) or polyurethane elastomer (PU) formulations requiring high safety metrics, ATBC is typically dosed between 5.0 and 20 parts per hundred rubber (phr). It functions as a safe matrix lubricant, lowering Mooney viscosity and maximizing elongation at break without causing surface blooming.

Partner with a Reliable Chemical Supplier

We provide premium-grade, phthalate-free Acetyl Tributyl Citrate (ATBC) plasticizer carefully processed to meet international technical benchmarks. Available in high-purity liquid drums, IBC totes, and bulk ISO tanks to ensure absolute processing precision inside your polymer mixing environment.