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Phthalate-Free Plasticizer DOA

An eco-friendly, non-phthalate adipate ester plasticizer engineered to deliver superior low-temperature flexibility, outstanding clarity, and excellent processing fluidics for PVC resins, synthetic rubbers, and food-contact packaging.

In modern polymer modification, outdoor vinyl processing, and automotive elastomer compounding, maintaining extreme flexibility under sub-zero thermal loads is a critical manufacturing milestone. Dioctyl Adipate (universally specified in international chemical sourcing as DOA or DEHA) stands as the ultimate industry benchmark for low-temperature, phthalate-free plasticization. Chemically identified as Bis(2-ethylhexyl) adipate (CAS No. 103-23-1), DOA is an aliphatic dicarboxylic acid ester produced as a water-white, low-viscosity clear liquid. Completely free of ortho-phthalate rings, DOA introduces maximum chain mobility into the polymer matrix, resulting in exceptional low-temperature shatter resistance and superior melt flow profiles during compounding.

Technical Product Specifications

Property / Parameter Standard Specification (Premium Grade)
Chemical Name Bis(2-ethylhexyl) adipate (Dioctyl Adipate / DOA)
CAS Number 103-23-1
Molecular Formula C22H34O4
Ester Content / Active Purity (%) ≥ 99.5%
Color (APHA / Pt-Co) ≤ 20 max
Density (g/cm³ at 20°C) 0.924 – 0.930 g/cm³
Acidity (as Adipic Acid, %) ≤ 0.01%
Flash Point (°C, Open Cup) ≥ 190 °C

Why Choose Our DOA Plasticizer?

  • ✓ Extreme Cold-Temperature Performance: Lowers the glass transition temperature (Tg) of polymers far more effectively than phthalate esters, keeping compounds flexible down to -60°C without crack vulnerability.
  • ✓ Fully Compliant Non-Phthalate Chemistry: Contains zero ortho-phthalate ring structures, ensuring seamless alignment with global regulatory protocols including EU REACH Annex XIV, US CA Prop 65, and FDA regulations.
  • ✓ Optimized Melt Flow & Fast Solvation: Its low native viscosity provides outstanding internal lubrication for polymers, dramatically boosting pigment wetting, processing speeds, and compound tack characteristics.

Primary Applications

Phthalate-free DOA is universally formulated across flexible PVC sheets, polar synthetic rubbers, and specialty food-contact films:

Food-Grade Cling Films & Wraps

The industry global standard plasticizer for fresh food cling films, poly packaging coatings, and container gaskets demanding ultra-high transparency and low migration risk.

Nitrile (NBR) & CR Rubber Engineering

Extensively incorporated into specialty elastomers to reduce compound Mooney viscosity, ease extrusion pressure, and maximize sub-zero elasticity for marine and automotive hoses.

Cold-Climate Wire & Cable Hoses

Formulated into premium outdoor electrical jacketing insulation, garden hoses, cold-storage curtains, and automotive weatherstripping strips.

⚠ Storage & Handling Guidelines

Maintaining correct warehouse climate parameters is vital to protect the active ester purity and excellent water-white clarity of Dioctyl Adipate (DOA). Although it possesses outstanding chemical stability and a high flash point, its aliphatic ester structure can undergo slow hydrolysis if exposed to prolonged moisture tracks, impacting its acid value and performance metrics.

  • • Warehouse Climate Control: Store all liquid drums, IBC totes, or bulk storage tanks within a thoroughly cool, dry, and well-ventilated dedicated warehouse footprint. Keep storage rows completely isolated from direct sunlight, open flames, steam pipes, or heating grids.
  • • Airtight Sealing Management: Ensure all container bungs, valves, and caps are tightly resealed immediately after any dispensing or sampling operations. Keeping containers hermetically sealed prevents ambient humidity absorption and safeguards the low-acidity quality of the ester.
  • • Shelf Life & Rotation Strategy: Under clean, temperature-controlled, and sealed environment parameters, our premium DOA plasticizer carries a certified shelf life of 24 months from the date of manufacture. Adhering to a strict First-In, First-Out (FIFO) material rotation system is recommended.

Frequently Asked Questions

What makes DOA uniquely suited for sub-zero low-temperature rubber applications? +
Unlike aromatic phthalate esters, the linear aliphatic dicarboxylic acid core of DOA introduces highly flexible molecular chains into the elastomer matrix. This lowers the glass transition temperature (Tg) of the composite far more effectively, ensuring that seals, industrial hoses, and profiles retain their elastic memory and reject brittle fracture down to -60°C.
Can DOA be blended with other plasticizers like DOTP or TOTM? +
Yes. Blending DOA with high-molecular-weight plasticizers like DOTP (for cost efficiency) or TOTM (for extraction resistance) is an excellent formulation practice. It allows compounders to engineer custom profiles that maximize low-temperature flex while suppressing the volatility or volatile migration traits often associated with pure aliphatic esters.
What is the standard recommended dosage range for DOA in polar synthetic rubbers? +
In typical polar formulations like Nitrile Rubber (NBR) or Chloroprene (CR) cold-storage gaskets and hoses, DOA is formulated between 5.0 and 20 parts per hundred rubber (phr). It significantly reduces Mooney viscosity and processing pressure during extrusion while boosting the final elongation parameters at break.

Partner with a Reliable Chemical Supplier

We provide premium-grade, phthalate-free Dioctyl Adipate (DOA) plasticizer carefully processed to meet international technical benchmarks. Available in high-purity liquid drums, IBC totes, and bulk ISO tanks to ensure absolute processing precision inside your polymer mixing environment.